东营凹陷民丰地区天然气生成机理与化学动力学研究   总被引：3，自引：0，他引：3  

王秀红  金强  胡晓庆  陈涛  宋国奇  王力  王娟  林腊梅  陈志伟 《沉积学报》2008,26(3):525-530

民丰地区天然气存在源岩热解和原油裂解成因的争议。本文采用高压釜封闭体系对该区烃源岩和原油样品分别进行了热模拟实验,从烃类气体生成过程、气态烃与部分单体烃生成动力学特征讨论了二者的生气机理,认为原油裂解比源岩热解生气活化能高30～40 kJ/mol,原油比源岩生气需要更高的热力学条件。模拟实验证实,成熟阶段源岩热解气与原油裂解气相比,以环烷烃和芳烃相对含量低为特征,与民丰地区产出的天然气组成更接近,据此认为该区天然气主要为源岩热解成因。  相似文献   

鄂尔多斯盆地天环坳陷北段奥陶系烃源岩特征及成熟演化史     

黄志刚  任战利  陈玉林  郑庆荣 《地质学报》2022,96(11):3967-3976

为研究天环坳陷北段下古生界天然气成藏规律，利用探井资料和有机地球化学方法，评价了天环坳陷北段奥陶系烃源岩特征并恢复其成熟演化史。天环坳陷北段奥陶系乌拉力克组和克里摩里组烃源岩有机碳含量和生烃潜量相对较高，烃源岩有机质丰度以中等—好为主，少部分为差烃源岩；三道坎组和桌子山组烃源岩以差为主。干酪根组分鉴定表明，天环坳陷北段奥陶系烃源岩主要为Ⅱ1~Ⅰ型干酪根，热演化程度高，处于生干气阶段。成熟演化史模拟显示，古生代—中生代早期地温梯度低，地层埋藏浅，烃源岩成熟演化程度低。燕山期，由于构造热事件，地温梯度迅速升高，早白垩世烃源岩经历的最高温度超过200℃，达到生气高峰期，早白垩世是油气成藏的主要时期。早白垩世之后，鄂尔多斯盆地整体抬升，地温梯度减小，生烃作用停止。  相似文献   

Experimental investigation of the elastic modulus of a fractal system—A model of fractured rocks     

T. L. Chelidze  H. Spetzler  I. C. Getting  Z. A. Avaliani 《Pure and Applied Geophysics》1990,134(1):31-43

The elastic properties of a physical model representing a damaged rock matrix were studied using a square lattice deformed under tensile stress. The elastic modulusM of such a system varies in agreement with percolation theory as|x–x _c | ^f , wherex is the damage parameter andx _c the threshold value of the damage parameter,f3.6. Atxx _c the scale dependence ofM can be expressed asML ^–f/v , whereL is the size of the sample andv the correlation exponent in percolation theory.The experimental results are of interest in assessing elastic properties in earthquake focal zones and fault zones in general.  相似文献   

Na depletion in modern adakites via melt / rock reaction within the sub-arc mantle     

X.L. Xiong  B. Xia  J.F. Xu  H.C. Niu  W.S. Xiao 《Chemical Geology》2006,229(4):273-292

Interaction between slab-derived melt and mantle peridotite and the role of slab melt as a metasomatizing agent in the sub-arc mantle is being increasingly recognized. Adakite, the slab melt erupted on the surface, usually exhibits anomalously high MgO, CaO, Cr and Ni contents that indicate interaction with mantle peridotitite. Here we note that Cenozoic adakites have Na₂O contents below 5.8 wt.% with ∼95% samples lower than 5.0 wt.%, and are generally depleted in this component relative to experimental basalt partial melts (mostly beyond 5.0 wt.% and up to 9.0 wt.% Na₂O) produced under 1.5-3.0 GPa conditions that are most relevant to adakite production. We interpret the adakite Na depletion to be also a consequence of the melt / rock reaction that takes place within the hot mantle wedge. During ascent and reaction with mantle peridotite, primary adakite melts gain mantle components MgO, CaO, Cr and Ni but lose Na₂O, SiO₂ and perhaps K₂O to the mantle, leading to Na-rich mantle metasomatism. Selective assimilation of predominately mantle clinopyroxene, some spinel and minor olivine at high T/P has been considered to be an important process in producing high-Mg adakites from primary low-Mg slab melts [Killian, R., Stern, C. R., 2002. Constraints on the interaction between slab melts and the mantle wedge from adakitic glass in peridotite xenoliths. Eur. J. Mineral. 14, 25-36]. In such a process, Na depletion in the assimilated melt is the result of dilution due to the increase in melt mass. Phase relationships in the reaction system siliceous melt + peridotite and quantitative calculation suggest that assimilation of mantle clinopyroxene, olivine and spinel and fractional crystallization of sodic amphibole and orthopyroxene, under conditions of moderate T/P and increasing melt mass, is also an important process that modifies the composition of adakites and causes the Na depletion.  相似文献   

湖南骑田岭花岗岩及其暗色微粒包体的地球化学与壳幔岩浆的混合作用   总被引：12，自引：2，他引：12  

付建明  谢才富  彭松柏  杨哓君  梅玉萍 《地球学报》2006,27(6):557-569

骑田岭岩体是南岭地区燕山早期具幔源组分贡献的花岗岩典型代表。其主体岩性为角闪黑云二长花岗岩和(角闪石)黑云正长花岗岩,其中发育暗色微粒包体和由暗色矿物组成的团块或条带。暗色微粒包体具有岩浆混合的大部分岩相学证据。如包体的浑圆状外形、塑性形变、冷凝边、斜长石An的“双峰式”分布、似环斑长石、针状磷灰石等。包体属于准铝质(A/KNC=0.72～1.00,平均0.85)钾玄岩系列岩石,寄主岩石为准铝或弱过铝质(A/KNC=0.89～1.06,平均0.97)高钾钙碱性系列的岩石。二者在主量和微量元素上表现出岩浆混合成因的演化趋势。包体与寄主岩石的同位素组成具趋同性,它们的ISr和εNd(t)值分别为0.71041～0.71263、-6.9～-5.3和0.70854～0.71416、-9.2～-5.1,均表现出壳幔混源花岗岩类岩石的特点。包体K-Ar年龄为152Ma,与其寄主岩石的形成年龄(155～161Ma)接近,显示岩浆混合作用发生的时间大致为晚侏罗世早期。对包体及其寄主岩石产出的构造背景和地球化学特征的综合分析表明,该岩体中的暗色微粒包体是在伸展作用的大地构造背景下,上涌的幔源基性岩浆及其诱发的长英质酸性岩浆混合作用的产物。  相似文献   

赣中变质岩带地质地球化学演化特征   总被引：1，自引：0，他引：1  

胡恭任  刘丛强  于瑞莲 《地球学报》2006,27(1):35-42

赣中变质岩带由结晶基底和褶皱基底组成。从结晶基底→褶皱基底,变质泥质岩类SI O2含量降低,AL2O3含量增加;变粒岩、石英片岩、硅质岩SI O2含量显著升高,AL2O3含量显著降低;NA2O含量显著降低,K2O的含量有明显的升高,NA2O/K2O值呈显著的降低趋势;FEO、MGO、TI O2及全铁含量(FE2O3 FEO)呈降低的趋势,但FE2O3升高,FE2O3/FEO值显著增高。铁族元素TI、V、CR升高,MN、CO、NI降低;亲铜元素ZN显著升高;大离子亲石元素LI、RB、SR显著降低,U、TH、BA显著升高,SR/BA值急剧降低;LA、CE、YB、NB、Y元素升高;稀土总量、轻稀土含量、轻重稀土比值、轻重稀土相互分离程度、EU亏损程度增加,说明它们原岩沉积环境的差异性,但它们的重稀土含量、LA/CE值、SM/ND值变化很小,稀土配分曲线相互平行反映它们源区岩石的一致性及继承性。从结晶基底→褶皱基底,岩石的ΕND(0)、(~(206)PB/~(204)PB)I、(~(207)PB/~(204)PB)I、(~(208)PB/~(204)PB)I值由低→高;地壳趋于成熟,结晶基底形成于岛弧环境,褶皱基底形成于活动大陆边缘环境。  相似文献   

冲击凿岩钎杆的瞬态动力学分析          下载免费PDF全文

周晔  张国榉 《探矿工程》2006,33(9):46-48

以ANSYS为平台，按照真实工作状态对凿岩钎杆进行了瞬态动力学分析，并对不同活塞形状下分析结果数据进行了比较，为冲击凿岩系统设计提供了理论依据。  相似文献   

PDC钻头切削齿破岩载荷规律的分析     

许爱 《探矿工程》2006,33(7):59-61

对PDC钻头冠部形状及不同的布齿密度和切削齿在不同的磨损状态下对PDC钻头切削齿受力的影响进行了分析；用相邻的3个切削齿之间的关系(不同的切削齿与切削齿之间的径向距离和切削齿之间的高度差)来分析PDC钻头冠部形状和切削齿布齿密度对切削齿受力的影响，以及将切削齿的磨损状态简化成与切削齿在钻头上装配方向垂直的平面来分析切削齿磨损状态对切削齿受力的影响。  相似文献   

双坡面临空岩质边坡滑动破坏模式下的稳定性分析     

周应华  周德培  邵江 《山地学报》2006,24(4):446-449

多数岩质边坡稳定性分析已基本解决了常走向单坡面临空的边坡平面滑动问题。然而,在路堑边坡工程和自然边坡中有很多边坡坡面并不是平面,它包含多个坡面。多坡面边坡包含两个或多个不同走向的坡面。多坡面边坡几何特征不同于单坡面边坡,所以滑动条件也不一样。在赤平投影图上,多坡面的滑动包络线是组成边坡的每个坡面单独投影包络线的组合。为了探讨方便,只讨论了双坡面临空岩质边坡的滑动破坏模式,并将其分为双坡面临空下的平面破坏和楔形体破坏。在赤平投影图上,双坡面滑动区域定义为双坡面边坡滑动包络图中两侧坡面的真倾线之间的面积。如果有一两个节理面真倾向线落在滑动区内,滑动破坏才可能发生。  相似文献   

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada     

Y.T. John Kwong 《中国地球化学学报》2006,25(B08):229-230

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.  相似文献